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Finite Size Effect (Critical Casimir Force)

We present experimental evidence for the Casimir effect within critical films of binary liquid mixtures possessing opposite boundary conditions (+-) by studying the thickness of these vapor-adsorbed films on a silicon wafer as a function of temperature near the critical temperature. Our results for two different critical mixtures demonstrate that the critical Casimir pressure scaling function J +-(y) scales with y=L/x, where L is the equilibrium film thickness and x is the bulk correlation length. Additionally, on approaching the critical temperature Tc an increase in the film thickness L is observed, implying that the sign of the universal Casimir amplitude D+-=J+-(0)/2 at Tc is positive, consistent with theoretical predictions. However, the magnitude of the Casimir amplitude that we measure is approximately two orders of magnitude smaller than that given by prevailing theories.
 

Further readings:   A. Mukhopadhyay and B. M. Law, Phys. Rev. Lett. 83, 772 (1999),
                            A. Mukhopadhyay and B. M. Law, Phys. Rev. E. 62, 5201 (2000).
 
 

Film thickness as a function of DT=T-Tc at fixed heights H=1.5 mm (diamond) and 3.3 mm (squares) for 2-methoxyethanol + methylcyclohexane (MM), and 3.4 mm (triangles) and 6.3 mm (inverted triangles) for methanol + hexane (MH), adsorbed on a vertical Si wafer.

The Casimir pressure scaling function J+-( y) obtained from a vertical Si wafer in the one-phase region for the two mixtures MH and MM. The function J +-( y) exhibits excellent scaling as a function of y=L/x.