Ruby laser was the first man made laser, which was build by Theodore Maiman in 1960.
Ruby is a synthetic crystal of Aluminum Oxide (Al2O3), and is more familiar in daily life as a precious stone for jewel.
The chemical structure of Ruby is of Al2O3 (which is called Sapphire), with impurity of about 0.05% (by weight) of Chromium Ions (Cr+3).
The active ion is Cr+3, which replace Al atom in the crystal. This ion causes the red color of the crystal. The impurity ion of Cr+3 is responsible for the energy levels which participate in the process of lasing.